Answer is as follow: (b) Carbon
Solution:
Step 1: Understanding the Chemical Reaction:
Concentrated sulphuric acid (H₂SO₄) acts as a powerful oxidizing agent. When it reacts with elemental carbon, it oxidizes the carbon to carbon dioxide while being reduced to sulphur dioxide.
Step 2: Identifying the Product Gases:
Balanced chemical equation: C + 2H₂SO₄(conc.) → CO₂ + 2SO₂ + 2H₂O
The gaseous products are Carbon dioxide (CO₂) and Sulphur dioxide (SO₂).
Step 3: Lime Water Test:
Both CO₂ and SO₂ react with lime water [Ca(OH)₂] to form white precipitates (CaCO₃ and CaSO₃), making the solution milky.
Step 4: Final Answer:
Carbon is the non-metal in this list that produces both gases simultaneously upon reaction with concentrated sulphuric acid.
Answer is as follow: (a) Copper metal is deposited at the negative electrode.
Solution:
Step 1: Understanding the Electrolysis Setup:
With active copper electrodes, the anode (positive) dissolves and the cathode (negative) receives deposits.
Step 2: Reaction at the Cathode (Negative):
Copper ions (Cu²⁺) move toward the cathode, gain electrons, and deposit as solid copper:
Cu²⁺ + 2e⁻ → Cu(s)
This increases the mass of the negative electrode.
Step 3: Reaction at the Anode (Positive):
The copper anode loses electrons and dissolves into the solution:
Cu(s) → Cu²⁺ + 2e⁻
This decreases the mass of the positive electrode.
Step 4: Final Answer:
Statement (a) is correct for this electrolytic process.
Answer is as follow: (b) 2
Solution:
Step 1: Identifying the Element:
Total electrons = 2 + 8 + 2 = 12. Element with atomic number 12 is Magnesium (Mg).
Step 2: Determining Valency:
Magnesium has 2 electrons in its outermost shell. It loses these to form Mg²⁺, a divalent cation.
Step 3: Writing the Hydroxide Formula:
Hydroxide (OH⁻) has valency 1. To balance Mg²⁺, two OH⁻ ions are needed. The chemical formula is Mg(OH)₂.
Answer is as follow: (c) C₂H₆ + Cl₂ → C₂H₅Cl + HCl
Solution:
Step 1: Understanding the Reaction Type:
Ethane is a saturated hydrocarbon (alkane). Alkanes undergo substitution reactions with halogens where hydrogen atoms are replaced one by one.
Step 2: The Role of UV Light:
UV light provides energy to break the Cl−Cl bond, initiating the free-radical chain reaction.
Step 3: Writing the Products:
One hydrogen atom from ethane (C₂H₆) is replaced by one chlorine atom to form chloroethane (C₂H₅Cl). The displaced hydrogen bonds with the second chlorine atom to form HCl.
Step 4: Final Answer:
The balanced equation is C₂H₆ + Cl₂ → C₂H₅Cl + HCl.
Answer is as follow: (a) 16
Solution:
Step 1: Understanding Ion Formation:
X → X²⁻ implies the atom X accepts 2 electrons to form an anion.
Step 2: Applying the Octet Rule:
Non-metals gain electrons to complete their valence shell (usually 8 electrons). An atom gaining 2 electrons must have had 6 valence electrons.
Step 3: Checking the Atomic Numbers:
• 16 (Sulphur): 2, 8, 6 → gains 2 electrons to become 2, 8, 8 → matches.
• 10 (Neon): 2, 8 → stable noble gas.
• 12 (Magnesium): 2, 8, 2 → usually loses 2 electrons to form Mg²⁺.
• 14 (Silicon): 2, 8, 4 → usually forms covalent bonds.
Step 4: Final Answer:
The atomic number is 16.
Answer is as follow: (c) 3
Solution:
Step 1: Understanding Salt Preparation:
Soluble salts can be made by reacting an acid with a metal, base, or carbonate. However, the “Metal + Acid” method only works for metals more reactive than hydrogen.
Step 2: Checking Copper’s Reactivity:
Copper is below hydrogen in the reactivity series, so it cannot displace hydrogen from dilute acids like HCl or H₂SO₄.
Step 3: Evaluating Alternatives:
Copper salts can be prepared by reacting copper oxide (a base) or copper carbonate with dilute acids, as these are neutralization/decomposition reactions not requiring hydrogen displacement.
Step 4: Final Answer:
Method 3 (Action of dilute acid on metals) cannot be used for copper.
Answer is as follow: (b) Sodium chloride
Solution:
Step 1: Comparing Bond Types:
The melting point of a substance depends on the strength of the forces holding its particles together.
Step 2: Analyzing the Options:
• Methane, Ammonia, Ethanol: Covalent compounds with weak intermolecular forces (Van der Waals or hydrogen bonding), usually gases or liquids at room temperature with very low melting points.
• Sodium chloride (NaCl): Ionic compound forming a giant 3D lattice held together by strong electrostatic forces between ions.
Step 3: Comparing Strengths:
Energy required to break ionic bonds is much higher than that needed to overcome intermolecular forces in covalent molecules.
Step 4: Final Answer:
Sodium chloride has the highest melting point.
Answer is as follow: (c) Both (A) and (R) are true and (R) is the correct explanation of (A).
Solution:
Step 1: Understanding Electrolytes:
The strength of an electrolyte depends on its ability to conduct electricity, which is determined by the presence of free, mobile ions.
Step 2: Comparing Dilute and Concentrated Acid:
Concentrated H₂SO₄ is largely molecular. Dilution with water causes the acid to ionize into H⁺ and SO₄²⁻ ions.
Step 3: Linking Ionization to Conductivity:
Dilute acid has a higher number of dissociated, mobile ions than concentrated acid, so it conducts electricity more effectively.
Step 4: Final Answer:
Both statements are true; the higher concentration of ions in dilute H₂SO₄ explains why it is a stronger electrolyte.
C₃H₈ + 5O₂ → 3CO₂ + 4H₂O
Answer is as follow: (b) 15 litres
Solution:
Step 1: Understanding Gay-Lussac’s Law:
According to Gay-Lussac’s Law of Combining Volumes, gases react in simple whole-number ratios by volume under the same temperature and pressure.
Step 2: Analyzing the Stoichiometry:
From the balanced equation: 1 volume of C₃H₈ reacts with 5 volumes of O₂ to produce 3 volumes of CO₂ and 4 volumes of H₂O.
Thus, 1 litre of propane produces 3 litres of CO₂.
Step 3: Calculating for 5 Litres:
Volume of CO₂ = 5 litres × 3 = 15 litres
Step 4: Final Answer:
The volume of CO₂ produced is 15 litres.
Answer is as follow: (c) propene
Solution:
Step 1: Analyzing the Molecular Formula:
The compound has 3 carbon atoms and 6 hydrogen atoms → molecular formula C₃H₆.
Step 2: Matching with General Formulas:
• Alkanes: CₙH₂ₙ₊₂ → C₃H₈ → Propane
• Alkenes: CₙH₂ₙ → C₃H₆ → Propene
• Alkynes: CₙH₂ₙ₋₂ → C₃H₄ → Propyne
Step 3: Verifying Unsaturation:
Unsaturated hydrocarbons contain double or triple bonds. C₃H₆ (propene) has one C=C double bond, making it unsaturated.
Step 4: Final Answer:
The compound is propene.
Answer is as follow: (a) (A) is true but (R) is false.
Solution:
Step 1: Understanding Water Electrolysis:
2H₂O(l) → 2H₂(g) + O₂(g)
Step 2: Evaluating the Assertion:
From the equation, 2 volumes of hydrogen are produced for every 1 volume of oxygen. Assertion (A) is true.
Step 3: Evaluating the Reason:
Water (H₂O) has hydrogen and oxygen in a volume ratio of 2:1 (and by mass 2:16 = 1:8). Reason (R) states 1:2, which is false.
Answer is as follow: (a) 1
Solution:
Step 1: Understanding Electrode Polarity:
The negative electrode is the cathode. Cations (positively charged ions) are attracted to the cathode for reduction.
Step 2: Identifying the Cation:
In molten Al₂O₃, the cation is Al³⁺.
Step 3: Describing the Cathode Reaction:
Al³⁺ ions gain 3 electrons each to form neutral aluminium atoms:
Al³⁺ + 3e⁻ → Al
Step 4: Final Answer:
Reaction 1 is the correct cathode reaction.
Answer is as follow:
(a) ZnO
(b) 2Br⁻ → Br₂ + 2e⁻
(c) 5.6 litres (calculation: Molecular weight O₂ = 32 g, 32 g occupies 22.4 L → 8 g occupies 22.4 × 8 / 32 = 5.6 L)
(d) Cu
(e) HCl
Solution:
(a) ZnO: Zinc oxide is amphoteric, reacts with acids and bases like KOH. CuO is basic and does not dissolve in KOH.
(b) 2Br⁻ → Br₂ + 2e⁻: At the anode, oxidation occurs; bromide ions lose electrons to form bromine gas.
(c) 5.6 L: Using molar volume at STP (22.4 L for 32 g of O₂), 8 g occupies 22.4 × 8 / 32 = 5.6 L.
(d) Cu: Copper is below hydrogen in the reactivity series, does not liberate H₂ with dilute HNO₃.
(e) HCl: HCl is polar due to large electronegativity difference; CCl₄ is non-polar due to symmetry canceling bond dipoles.
Identify:
Answer:
(a) Anion: Cl⁻ (Chloride ion)
(b) Cation: Cu²⁺ (Copper(II) ion)
Solution:
(a) Anion: Chloride ion reacts with AgNO₃ to form a white precipitate of AgCl, which dissolves in excess NH₄OH forming [Ag(NH₃)₂]⁺, confirming Cl⁻.
(b) Cation: Copper(II) ions react with NaOH to give pale blue Cu(OH)₂ precipitate, which is a characteristic test for Cu²⁺.
N aNO₃ + H₂SO₄ <200°C → NaHSO₄ + HNO₃
Answer:
(a) Reason for temperature < 200°C:
(b) Use of concentrated H₂SO₄:
Answer:
(a) Element A: Nitrogen (N)
(b) Formula of compound with hydrogen: NH₃ (Ammonia)
(c) Electron Dot Structure:
Nitrogen atom (center) shares three of its five valence electrons with three Hydrogen atoms, leaving one lone pair.
H
|
H — N ••
|
H
Here, •• represents the lone pair on nitrogen, and each H shares one electron with N.
Answer:
(a) Dehydrohalogenation of ethylene dibromide:
C₂H₄Br₂ + 2KOH(alc.) → C₂H₂ + 2KBr + 2H₂O
Product: Ethyne (Acetylene)
(b) Reaction of excess ammonia with chlorine:
8NH₃ + 3Cl₂ → 6NH₄Cl + N₂
Products: Ammonium chloride (white fumes) and Nitrogen gas
(c) Dehydration of cane sugar by concentrated H₂SO₄:
C₁₂H₂₂O₁₁ + conc. H₂SO₄ → 12C + 11H₂O
Concentrated H₂SO₄ removes water, leaving a black spongy mass of sugar charcoal
Answer:
(a) Acetic acid vs. Sulphuric acid:
(b) Electrolyte vs. Metallic conductor:
Solution:
Based on the descriptions:
(a) Which element would be most difficult to reduce?
Element P. Being highly electropositive, it readily loses electrons (oxidizes), so gaining electrons (reduction) is very difficult.
(b) Smallest atomic radius?
Element R. Atomic radius decreases across a period from left to right due to increasing nuclear charge, making R the smallest.
(c) Decreasing order of ionization potential:
Ionization potential increases across a period. Therefore, decreasing order: R > Q > P